Electrodeposition and Characterization of Zinc Oxide Nanostructures for ZnO-based Dye-Sensitized-Solar-Cells PDF Download. Download free ebook of Electrodeposition and Characterization of Zinc Oxide Nanostructures for ZnO-based Dye-Sensitized-Solar-Cells in PDF format or read online by Servane Haller Published on 2012 by
Dye Sensitized Solar Cells are an original alternative to conventional photovoltaic devices. With efficiencies up to 12% and low production costs, it is now a serious technology for mass market production. Development of new deposition techniques and original morphologies for the anode, which is a key component of the device, is expected to make this technology more competitive. In this work, we have used electrodeposition to prepare and characterize Zinc Oxide nanostructures. This technique is very suitable for preparation of nanostructured material with controlled morphology at nanoscale and very low cost of production. After introducing the context of Dye-Sensitized Solar cells with the most advanced results and the current reflections on the physical aspects of these devices, we have prepared a variety of promising nanostructures. Nanoporous ZnO layers have been adapted for deposition on ZnO-Al as substrate and a highly organized structure could be obtained. Hierarchical structures composed of highly conductive nanowires and nanoporous structure with high surface area have been synthesized. Electrochemical Impedance Spectroscopy has been carried out to characterize these nanostructures in order to investigate both optoelectronic and geometrical aspects. In a third part, ZnO-based DSSC have been prepared. The performance of the nanostructured ZnO layers and the influence of the substrate used for deposition have been investigated. Photovoltaic conversion efficiency up to 5.2% could be obtained in the optimized conditions.
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